Complex Amphiphilic Hyperbranched Fluoropolymers by Atom Transfer Radical Self-Condensing Vinyl (Co)polymerization
نویسندگان
چکیده
منابع مشابه
Recent Progress on Hyperbranched Polymers Synthesized via Radical-Based Self-Condensing Vinyl Polymerization
This short review article summarizes recent reports on using controlled radical polymerization (CRP) of inimers (compounds containing initiating group and vinyl group in one molecule) or transmers (compounds containing chain transfer group and vinyl group in one molecule) for the synthesis of hyperbranched polymers. These inimers and transmers that carry numerous functional groups could be homo...
متن کاملSurface-grafted Hyperbranched Polymers by Self- Condensing Vinyl (co)polymerization via Atrp
Introduction Highly branched polymers play an increasingly important role in interface and surface sciences, since their distinctive chemical and physical properties can be used advantageously as functional surfaces and as interfacial materials. Hyperbranched polymers grafted onto surfaces have also become a field of growing interest. Depending upon the substrates, it can be divided into 3D, 2D...
متن کاملSequence-regulated vinyl copolymers with acid and base monomer units via atom transfer radical addition and alternating radical copolymerization†
Mainand side-chain sequence-regulated vinyl copolymers with acid and base monomer units were prepared using atom transfer radical addition (ATRA) and alternating radical copolymerization. A series of maleimide-ended sequence-regulated “oligomonomers” were prepared by ATRA of t-butyl acrylate (tBA: Ap) (i.e., a protected acrylic acid (A)) or an amine-functionalized acrylate, (2-(dimethylamino)et...
متن کاملKinetics of Self-Condensing Vinyl Hyperbranched Polymerization in Three-Dimensional Space
Self-condensing vinyl hyperbranched polymerization (SCVP) with A-B* type monomer is simulated applying Monte Carlo method using 3d bond fluctuation lattice model in three-dimensional space. The kinetics of SCVP with zero active energy of reaction is studied in detail. It is found that the maximal number–average and weight–average polymerization degrees and the maximal molecular weight distribut...
متن کاملpoly(vinyl acetate)-based block copolymer/clay nanocomposites prepared by in situ atom transfer radical polymerization
atom transfer radical polymerization of styrene (st) and methyl methacrylate (mma) was performed at 90oc in the absence and presence of nanoclay (cloisite 30b). trichloromethyl-terminated poly(vinyl acetate) telomerand cucl/ pmdeta were used as a macroinitiator and catalyst system, respectively. the experimental results showed that the atom transfer radical polymerization of st and mma in the a...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Macromolecules
سال: 2007
ISSN: 0024-9297,1520-5835
DOI: 10.1021/ma0628937